Low temperature isolation of a dinuclear silver complex of the cyclotetraphosphane [ClP(μ-PMes*)]2.
نویسندگان
چکیده
The reaction of the cyclotetraphosphane [ClP(μ-PMes*)]2 (, Mes* = 2,4,6-tri-tert-butylphenyl) with Ag[Al(OR(F))4] (R(F) = CH(CF3)2) resulted in a labile, dinuclear silver complex of , which eliminates AgCl above -30 °C. Its properties were investigated by spectroscopic methods, single crystal X-ray diffraction and DFT calculations.
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عنوان ژورنال:
- Dalton transactions
دوره 45 2 شماره
صفحات -
تاریخ انتشار 2016